Peek-O-Matic is a free AppleScript which allows you to run an application as another user. You bind an app permanently to the script by drag-and-drop and then it asks for a user name and remembers that, too. Henceforth, launching Peek-O-Matic launches above app as above user. You can choose whether to enter a password each time or have it stored in the Keychain.
Automatically launch, quit, or kill applications when others are launched or quit.
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